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Totalsynthese des Marinen Makrolids Palmerolid A: Zugang zu einem Naturstoff mit Pharmakologisch Vielversprechendem Wirkprofil (German Edition)



By: Julia Sunner(Author)

Language: German

Genre: Science & Nature

Publisher: Springer Vieweg; 2012 edition (10 Sept. 2012)

Format: pdf doc docx mobi djvu epub ibooks (*An electronic version of a printed book that can be read on a computer or handheld device designed specifically for this purpose.)

The original title of the book: Totalsynthese des Marinen Makrolids Palmerolid A: Zugang zu einem Naturstoff mit Pharmakologisch Vielversprechendem Wirkprofil (German Edition)

Der Naturstoff Palmerolid A wurde im Jahr 2006 erstmals isoliert und zeigte in zellbiologischen Untersuchungen eine sehr starke und außergewöhnlich selektive cytotoxische Aktivität gegenüber ausgewähltenKrebszelllinien. Als 20-gliedriges Makrolacton mit fünf Stereozentren, mehreren isolierten und konjugierten Doppelbindungseinheiten und einer Dienamid-tragenden Seitenkette bietet der hochfunktionalisierte Naturstoff ausstruktureller Sicht für den Synthesechemiker interessante Herausforderungen. Im Rahmen dieser Studie wurde eine Strategie entwickelt, die den totalsynthetischen Zugang zu diesem hochpotenten Molekül ermöglicht. Über die hierbeschriebene Synthesesequenz konnte eine bemerkenswerte Menge des Naturstoffs zur Verfügung gestellt werden, um seine pharmakologischen und toxikologischen Eigenschaften ausführlich zu untersuchen.

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